Organic Chemistry: 100 Must-Know Mechanisms

Roman Valiulin

Published by De Gruyter 2020

Organic Chemistry: 100 Must-Know Mechanisms

Roman Valiulin

In the series De Gruyter Textbook

https://doi.org/10.1515/9783110608373

Overview
Contents

About this book

This book summarizes 100 essential mechanisms in organic chemistry ranging from classical such as the Reformatsky Reaction from 1887 to recently elucidated mechanism such as the copper(I)-catalyzed alkyne-azide cycloaddition. The reactions are easy to grasp, well-illustrated and underpinned with explanations and additional information.

Organic chemistry at a glance: straightforward and easy-to-grasp depiction of 100 crucial mechanisms in organic chemistry

Author / Editor information

Roman Valiulin, Cambridge, USA.

Topics

Frontmatter Publicly Available Download PDF	I
Preface and Overview Publicly Available Download PDF	VII
Contents Publicly Available Download PDF	1
List of Acronyms and Abbreviations Requires Authentication Unlicensed Licensed Download PDF	6
1. Electrophilic Addition Mechanism Requires Authentication Unlicensed Licensed Download PDF	10
2. Nucleophilic Substitution Mechanism Requires Authentication Unlicensed Licensed Download PDF	12
3. Aromatic Electrophilic Substitution Mechanism Requires Authentication Unlicensed Licensed Download PDF	14
4. Aromatic Nucleophilic Substitution Mechanism Requires Authentication Unlicensed Licensed Download PDF	16
5. Aromatic Radical Nucleophilic Substitution Mechanism Requires Authentication Unlicensed Licensed Download PDF	18
6. Elimination Mechanism Requires Authentication Unlicensed Licensed Download PDF	22
7. Acyloin Condensation Requires Authentication Unlicensed Licensed Download PDF	26
8. Alkyne Zipper Reaction Requires Authentication Unlicensed Licensed Download PDF	28
9. Arbuzov Reaction Requires Authentication Unlicensed Licensed Download PDF	30
10. Arndt‒Eistert Synthesis Requires Authentication Unlicensed Licensed Download PDF	32
11. Baeyer‒Villiger Oxidation Requires Authentication Unlicensed Licensed Download PDF	34
12. Barton Decarboxylation Requires Authentication Unlicensed Licensed Download PDF	36
13. Baylis‒Hillman Reaction Requires Authentication Unlicensed Licensed Download PDF	38
14. Beckmann Rearrangement Requires Authentication Unlicensed Licensed Download PDF	40
15. Benzoin Condensation Requires Authentication Unlicensed Licensed Download PDF	42
16. Benzyne Mechanism Requires Authentication Unlicensed Licensed Download PDF	44
17. Bergman Cyclization Requires Authentication Unlicensed Licensed Download PDF	46
18. Birch Reduction Requires Authentication Unlicensed Licensed Download PDF	48
19. Bischler‒Napieralski Cyclization Requires Authentication Unlicensed Licensed Download PDF	50
20. Brown Hydroboration Requires Authentication Unlicensed Licensed Download PDF	52
21. Buchwald‒Hartwig Cross Coupling Requires Authentication Unlicensed Licensed Download PDF	54
22. Cannizzaro Reaction Requires Authentication Unlicensed Licensed Download PDF	56
23. Chan‒Evans‒Lam Cross Coupling Requires Authentication Unlicensed Licensed Download PDF	58
24. Chichibabin Amination Requires Authentication Unlicensed Licensed Download PDF	60
25. Claisen Condensation Requires Authentication Unlicensed Licensed Download PDF	62
26. Claisen Rearrangement Requires Authentication Unlicensed Licensed Download PDF	64
27. Cope Elimination Requires Authentication Unlicensed Licensed Download PDF	66
28. Cope Rearrangement Requires Authentication Unlicensed Licensed Download PDF	68
29. Criegee & Malaprade Oxidation Requires Authentication Unlicensed Licensed Download PDF	70
30. CuAAC Requires Authentication Unlicensed Licensed Download PDF	72
31. Curtius Rearrangement Requires Authentication Unlicensed Licensed Download PDF	74
32. Darzens Condensation Requires Authentication Unlicensed Licensed Download PDF	78
33. Dess‒Martin Oxidation Requires Authentication Unlicensed Licensed Download PDF	80
34. Diazotization (Diazonium Salt) Requires Authentication Unlicensed Licensed Download PDF	82
34. Diazotization (Diazonium Salt) Requires Authentication Unlicensed Licensed Download PDF	84
36. Di‒π‒Methane Rearrangement Requires Authentication Unlicensed Licensed Download PDF	86
37. Favorskii Rearrangement Requires Authentication Unlicensed Licensed Download PDF	88
38. Fischer Indole Synthesis Requires Authentication Unlicensed Licensed Download PDF	90
39. Friedel‒Crafts Acylation & Alkylation Requires Authentication Unlicensed Licensed Download PDF	92
40. Gabriel Synthesis Requires Authentication Unlicensed Licensed Download PDF	94
41. Gewald Reaction Requires Authentication Unlicensed Licensed Download PDF	96
42. Glaser–Eglinton–Hay Coupling Requires Authentication Unlicensed Licensed Download PDF	98
43. Grignard Reaction Requires Authentication Unlicensed Licensed Download PDF	100
44. Grob Fragmentation Requires Authentication Unlicensed Licensed Download PDF	102
45. Haloform Reaction Requires Authentication Unlicensed Licensed Download PDF	104
46. Heck Cross Coupling Requires Authentication Unlicensed Licensed Download PDF	106
47. Hell–Volhard–Zelinsky Reaction Requires Authentication Unlicensed Licensed Download PDF	108
48. Hiyama Cross Coupling Requires Authentication Unlicensed Licensed Download PDF	110
49. Hofmann Elimination Requires Authentication Unlicensed Licensed Download PDF	112
50. Horner–Wadsworth–Emmons Olefination Requires Authentication Unlicensed Licensed Download PDF	114
51. Jones Oxidation Requires Authentication Unlicensed Licensed Download PDF	116
52. Kucherov Reaction Requires Authentication Unlicensed Licensed Download PDF	118
53. Kumada Cross Coupling Requires Authentication Unlicensed Licensed Download PDF	120
54. Ley–Griffith Oxidation Requires Authentication Unlicensed Licensed Download PDF	122
55. Liebeskind–Srogl Cross Coupling Requires Authentication Unlicensed Licensed Download PDF	124
56. Mannich Reaction Requires Authentication Unlicensed Licensed Download PDF	126
57. McMurry Coupling Requires Authentication Unlicensed Licensed Download PDF	128
58. Meerwein–Ponndorf–Verley Reduction Requires Authentication Unlicensed Licensed Download PDF	130
59. Michael Addition Requires Authentication Unlicensed Licensed Download PDF	132
60. Minisci Reaction Requires Authentication Unlicensed Licensed Download PDF	134
61. Mitsunobu Reaction Requires Authentication Unlicensed Licensed Download PDF	136
62. Miyaura Borylation Requires Authentication Unlicensed Licensed Download PDF	138
63. Mukaiyama RedOx Hydration Requires Authentication Unlicensed Licensed Download PDF	140
64. Nazarov Cyclization Requires Authentication Unlicensed Licensed Download PDF	142
65. Nef Reaction Requires Authentication Unlicensed Licensed Download PDF	144
66. Negishi Cross Coupling Requires Authentication Unlicensed Licensed Download PDF	146
67. Norrish Type I & II Reaction Requires Authentication Unlicensed Licensed Download PDF	148
68. Olefin (Alkene) Metathesis Requires Authentication Unlicensed Licensed Download PDF	150
69. Oppenauer Oxidation Requires Authentication Unlicensed Licensed Download PDF	154
70. Ozonolysis Requires Authentication Unlicensed Licensed Download PDF	156
71. Paal–Knorr Syntheses Requires Authentication Unlicensed Licensed Download PDF	158
72. Paternò–Büchi Reaction Requires Authentication Unlicensed Licensed Download PDF	162
73. Pauson–Khand Reaction Requires Authentication Unlicensed Licensed Download PDF	164
74. Peptide (Amide) Coupling Requires Authentication Unlicensed Licensed Download PDF	166
75. Pictet–Spengler Reaction Requires Authentication Unlicensed Licensed Download PDF	170
76. Pinacol–Pinacolone Rearrangement Requires Authentication Unlicensed Licensed Download PDF	172
77. Polonovski Reaction Requires Authentication Unlicensed Licensed Download PDF	174
78. Prilezhaev Epoxidation Requires Authentication Unlicensed Licensed Download PDF	176
79. Prins Reaction Requires Authentication Unlicensed Licensed Download PDF	178
80. Pummerer Rearrangement Requires Authentication Unlicensed Licensed Download PDF	180
81. Ramberg–Bäcklund Rearrangement Requires Authentication Unlicensed Licensed Download PDF	182
82. Reformatsky Reaction Requires Authentication Unlicensed Licensed Download PDF	184
83. Robinson Annulation Requires Authentication Unlicensed Licensed Download PDF	186
84. Shapiro Reaction Requires Authentication Unlicensed Licensed Download PDF	188
85. Sonogashira Cross Coupling Requires Authentication Unlicensed Licensed Download PDF	190
86. Staudinger Reaction Requires Authentication Unlicensed Licensed Download PDF	192
87. Steglich Esterification Requires Authentication Unlicensed Licensed Download PDF	194
88. Stille Cross Coupling Requires Authentication Unlicensed Licensed Download PDF	196
89. Suzuki Cross Coupling Requires Authentication Unlicensed Licensed Download PDF	198
90. Swern Oxidation Requires Authentication Unlicensed Licensed Download PDF	200
91. Ugi Reaction Requires Authentication Unlicensed Licensed Download PDF	202
92. Ullmann Aryl–Aryl Coupling Requires Authentication Unlicensed Licensed Download PDF	204
93. Upjohn Dihydroxylation Requires Authentication Unlicensed Licensed Download PDF	206
94. Vilsmeier–Haack Reaction Requires Authentication Unlicensed Licensed Download PDF	208
95. Wacker Oxidation Requires Authentication Unlicensed Licensed Download PDF	210
96. Wagner–Meerwein Rearrangement Requires Authentication Unlicensed Licensed Download PDF	212
97. Weinreb Ketone Synthesis Requires Authentication Unlicensed Licensed Download PDF	214
98. Wittig Reaction Requires Authentication Unlicensed Licensed Download PDF	216
99. Wohl–Ziegler Reaction Requires Authentication Unlicensed Licensed Download PDF	218
100. Wolff–Kishner Reduction Requires Authentication Unlicensed Licensed Download PDF	220
Acknowledgments Requires Authentication Unlicensed Licensed Download PDF	223
Bibliography and References Requires Authentication Unlicensed Licensed Download PDF	225

(Deutsch)

Language: English
Publisher: De Gruyter
Audience: Students, Organic Chemists
Pages
- Front matter: 10
- Main content: 239
Illustrations
- Coloured Illustrations: 319
- Tables: 5
Keywords: Organic Chemistry; Reaction Mechanisms; Chemical Sythesis

eBook

Published: April 20, 2020
ISBN: 9783110608373